热力学参量组完备性法则及其应用

The Completeness of the Group of Thermodynamics Variables and Its Application

提出了描述热力学系统状态的热力学参量组完备性法则，并把它用于吉布斯相律的正确导出．还指出了原有的吉布斯相律证明中存在的问题，又提出并证明了适合于半开放系统和生物系统相变的自由度律．

The rule of the completeness of the group of thermodynamic variables has been put forward.The rule has been applied to the exact deduction of Gibbs phase rule.The some mistakes of the present deduction of the phase rule has also pointed out.Besides,the law of degree of freedom of phase transition suitable to semi-opened system and biological system has been put for ward and proved.