3-氨基-4-氯肟基呋咱的合成实验研究

Experimental Study on the Synthesis of 3-Amino-4-chloroximinofurazan

由丙二腈经两步反应合成出了标题化合物——3-氨基4-氯肟基呋咱。用IR、MS、^1H NMR,^13C NMR、元素分析和紫外线吸收光谱法对标题化合物及其中间体——3-氨基4-氨基肟基呋咱进行了分子结构表征。标题化合物总得率41．5％。对标题化合物的合成反应过程进行了理论推导和实验验证，这对优化标题化合物的合成有一定的指导作用。

The title compound 3-amino-4-chloroximinofurazan （ACOF） is synthesized by using dicyanoprupane as initial material through two steps reaction. The molecular structures of title compound and the intermediate 3-amino-4-amnioximinofurazan（AAOF） were identified by IR,MS, ^1H NMR, ^13C NMR,elemental analysis and ultra-violet absorption spectrometry. The yield of title compound is 41.5%. The synthesis reactions of title compound were theoretically explained and demonstrated by experiments, which could optimize the synthesis conditions of title compound.