纳米硫化锌球壳的高压相变研究

Pressure Induced Phase Transition of Nano Zinc Sulfide Shell

采用同步辐射能量色散X射线衍射(EDEX)技术和金刚石对顶砧高压装置,对纳米硫化锌球壳进行了原位高压X射线衍射实验。最高压力达33.3 GPa。常压下纳米硫化锌球壳为纤锌矿结构和闪锌矿结构共存的混相结构。压力达到11.2 GPa时,纳米硫化锌空心球中的纤锌矿结构全部转变为闪锌矿结构。压力达到16.0 GPa时,发生了由闪锌矿结构向岩盐矿结构的相变,在17.5 GPa和21.0 GPa时分别出现未知峰,33.3 GPa时基本完全转变为岩盐矿结构。两个相变均为可逆相变。

In situ energy dispersive X-ray diffraction measurements on nano zinc sulfide shell have been carried out by using diamond anvil cell with synchrotron radiation. The highest pressure is 33.3 GPa in the experiment. The raw materials contain two structures of ZnS, which are wurtzite and zinc blende respectively. With increasing pressure, the wurtzite structre was transformed to zinc blende structure at 11.2 GPa. A phase transition from zinc blende structure to rocksalt structure occurred as the pres- sure reached to 16.0 GPa. Two unknown diffraction peaks were found in the range of pressure from 17.5 GPa to 21.0 GPa. The rocksalt structure existed as the pressure reached to 33.3 GPa. Both of the phase transitions are reversible.