气液色谱法研究双—（o，o′—二正辛基二硫代磷酸酯）合镍（Ⅱ）与环戊酮加合反应的热力学性质

Study on the Electrolytic Formation of AgO on the Silver Electrode in KOH Solution with In-Situ X-ray Diffration

用气液色谱法研究了双—（ｏ，ｏ′—二正辛基二硫代磷酸酯）合镍（Ⅱ）与环戊酮加合反应的热力学性质，测定了３３３．２～３６３．２Ｋ范围内加合反应的平衡常数，用最小二乘法求得反应的ΔＨ和ΔＳ．

Cyclic voltammetry has been used to study the electrolytic formation of AgO at a silver electrode in aqeous KOH solutions.A range of concentrations of KOH and sweep rates have been used.The conditions under which an anodic peak appears on the negative-going sweep have been determined. The products AgO which formed at the reversed peak are in situ characterized with X-ray diffraction.