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碳族元素氢化物与氢反应的对比

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摘要 对碳族元素氢化物与氢反应体系应用SVRT模型进行了4维含时的量子动力学计算,对其初始振动、转动激发进行了对比研究.还计算了初始基态下H+SiH4,H+GeH4两反应的速率常数并进行比较,进而从理论上找出此类反应的一些规律.验证了理论方法以及势能面的正确性.
出处 《中国科学(G辑)》 CSCD 2005年第6期643-650,共8页
基金 国家自然科学基金资助项目(批准号:10174046 10474060 10504017)
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