摘要
Photoluminescent （PL） and cathodoluminescent （CL） properties of rare earths （Sc^3＋ , La^3＋ , Gd^3＋ and Lu^3＋ ） doped （Y0.97Tb0.03）2SiO5 were studied. Rare earth doping clearly influences PL and CL properties of Y2SiO5 ： Tb. For La^3＋ doped system, PL intensity increases nearly 10 % at x = 0.05 whereas for Lu^3＋ doped system, the intensity increases about 20% at x = 0.20. Gd^3 ＋ doping and Sc^3＋ doping reduce the intensity; at x = 0.3, it is reduced about 30% for Gd^3＋ doped system and about 15 % for Sc^3＋ doped system, respectively. Quenching concentration of activator became higher in rare earth doped samples, which may be understood by that the rare earth dopants might dilute the concentration of the activator. Additionally, doping also influences the color saturation of Y2SiO5 ： Tb. Sc^3＋ , La^3＋ , and Gd^3doping improve the color saturation, whereas Lu^3＋ doping decreases the color saturation. CL measurements show that CL intensity increases for all rare earths doped systems. The energy transfer from Gd^3＋ to Tb^3＋ was discussed.
Photoluminescent （PL） and cathodoluminescent （CL） properties of rare earths （Sc^3＋ , La^3＋ , Gd^3＋ and Lu^3＋ ） doped （Y0.97Tb0.03）2SiO5 were studied. Rare earth doping clearly influences PL and CL properties of Y2SiO5 ： Tb. For La^3＋ doped system, PL intensity increases nearly 10 % at x = 0.05 whereas for Lu^3＋ doped system, the intensity increases about 20% at x = 0.20. Gd^3 ＋ doping and Sc^3＋ doping reduce the intensity; at x = 0.3, it is reduced about 30% for Gd^3＋ doped system and about 15 % for Sc^3＋ doped system, respectively. Quenching concentration of activator became higher in rare earth doped samples, which may be understood by that the rare earth dopants might dilute the concentration of the activator. Additionally, doping also influences the color saturation of Y2SiO5 ： Tb. Sc^3＋ , La^3＋ , and Gd^3doping improve the color saturation, whereas Lu^3＋ doping decreases the color saturation. CL measurements show that CL intensity increases for all rare earths doped systems. The energy transfer from Gd^3＋ to Tb^3＋ was discussed.
基金
Project supported bythe State Key Programfor Basic Research of China (G1998061306) ,the National Natural Science Foun-dationof China (20221101) ,the Natural Science Foundation of Shaanxi Province (2004B31) and Youth Foundation ofShaanxi Normal University
