摘要
Reaction of a preformed cluster [{(η5-C5Me5)WS3}3Cu7(MeCN)9](PF6)4 (1) in MeCN with LiCl and PPh3 gave rise to a tetranuclear cationic cluster [(η5-C5Me5)WS3{Cu(PPh3)}3Cl](PF6) (2). The title compound 2 was char- acterized by elementary analysis, IR, UV-Vis, 1H NMR, and its crystal structure was determined by X-ray single crystal diffraction. It belongs to monoclinic, space group P21/c with a=1.7998(4) nm, b=2.0836(4) nm, c=1.9135(4) nm, β=113.63(3)°, V=6.574(3) nm3, Z=4. The cluster cation [(η5-C5Me5)WS3{Cu(PPh3)}3Cl]+ of 2 contains a strongly distorted, cubane-like structure [WS3Cu3Cl] in which one Cl weakly fills into the void of the nido-like [WS3Cu3] fragment with three relatively long Cu-Cl distances. CCDC: 270415.
Reaction of a preformed cluster [(η^5-C5Me5)WS3{Cu(PPh3))3Cl](PF6)4 (1) in MeCN with LiCl and PPh3 gave rise to a tetranuclear cationic cluster [(η^5-C5Me5)WS3{Cu(PPh3))3Cl](PF6)(2). The title compound 2 was characterized by elementary analysis, IR, UV-Vis, ^1H NMR, and its crystal structure was determined by X-ray single crystal diffraction. It belongs to monoclinic, space group P21/c with a=1.799 8(4) nm, b=2.083 6(4) nm, c=1.913 5(4) nm, β3=113.63(3)°, V=6.574(3) nm^3, Z=4. The cluster cation [(η^5-C5Me5)WS3{Cu(PPh3))3Cl]^+ of 2 contains a strongly distorted, cubane-like structure [WS3Cu3Cl] in which one Cl weakly fills into the void of the nido-like [WS3Cu3] fragment with three relatively long Cu-Cl distances. CCDC: 270415.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2006年第1期187-190,共4页
Chinese Journal of Inorganic Chemistry
基金
江苏省自然科学研究基金资助项目(No.BK2004205)
江苏省有机合成重点实验室开放基金资助项目(No.JSK001)
苏州大学青年教师研究基金项目(No.Q3109510)。
关键词
钨簇合物
铜簇合物
晶体结构
合成
tungsten cluster
copper cluster
crystal structure
synthesis