期刊文献+

由煤系高岭土合成小晶粒NaY分子筛及其应用 被引量:21

Synthesis and Application of NaY Zeolite from Coal-Bearing Kaolin
下载PDF
导出
摘要 利用不同的方法分别合成了常规尺寸和纳米NaY分子筛,并采用XRD和TEM手段对合成样品进行了表征,小晶粒分子筛其粒径小于100 nm。催化裂化试验表明,纳米分子筛可提高大分子转化能力及改善产物选择性,比常规晶粒尺寸分子筛更为优越的性能。 NaY zeolites with nanosize and normal size were successfully synthesized through different ways. The X-ray diffraction and TEM results indicated that the crystal zeolite product had an average size under 100 nm. Fluid catalytic cracking (FCC) catalysts was prepared respectively from the two zeolites. FCC test results showed that compared with catalyst containing conventionally hydrothermal synthesized NaY zeolite, catalyst containing nanosized zeolite exhibited good big molecule cracking performance and excellent selectivity.
出处 《化学工业与工程》 CAS 2006年第1期18-20,共3页 Chemical Industry and Engineering
基金 中国石油化工总公司资助项目(项目编号:X503007)
关键词 高岭土 纳米 NAY分子筛 催化裂化 Kaolin nano size NaY zeolite catalytic cracking
  • 相关文献

参考文献11

  • 1RAJAGOPALAN K, PETERS A W, EDWARDS G C.Influence of zeolite particle-size on selectivity during fluid catalytic cracking[J]. Appl Catal, 1986,23( 1 ):69 - 99.
  • 2SHIRALKAR V P,JOSHI P N, EAPEN M J, et al. Synthesis of ZSM-5 with variable crystallite size and its influence on physicochemical properties [ J ]. Zeolites, 1991, 11: 511-516.
  • 3PUS B, INUL T. Influence of crystallite size on catalytic performance of HZSM-5 prepared by different methods in 2,7-dimethylnaphthalene isomerization [ J ]. Zeolites, 1996, 17:334-339.
  • 4HERRMANN C, HAAS J, FETYING F. Effect of the crystal size on the activity of ZSM-5 catalysts in various reactions[J]. Appl Catal, 1987,35:299 - 310.
  • 5VALTCHEV V, MINTOVA S, DIMOV V, et al.Tribochemical activation of seeds for rapid crystallization of zeolite Y[J] . Zeolites, 1995,15: 193 - 197.
  • 6DUTFA P K, BRONIC J. Mechanism of zeolite formation-seed gel interaction [ J ]. Zeolites, 1994,14: 250 - 255.
  • 7SCHOEMAN B J, STERTE J, OTYERSTEDT J E. Synthesis and size tailoring of colloidal zeolite particles [ J ]. J Chem Soc, Chem Commun, 1993,12:994 - 995.
  • 8MCDANIED C V, MAHER P K, PILATO J M. Preparation of zeolites [ P ]. US: 4166099,1979 - 08 - 28.
  • 9LINDNER T, LECHERT H. Chelate ligands as mineralizing agents in hydrothermal synthesis of faujasite-type zeolites: A kinetic study[J]. Zeolites, 1996,16: 196 - 206.
  • 10SCHOEMAN B J, STERTE J, OTIZRSTEDT J E. Colloidal zeolite suspensions [ J ]. Zeolites, 1994, 14: 110 - 116.

同被引文献337

引证文献21

二级引证文献95

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部