以可再生资源二氧化碳为原料合成环状碳酸酯

Syntheses of Cyclic Carbonates Starting from Typical Renewable Carbon Dioxide

综述了近几年来由可再生资源二氧化碳制备环状碳酸酯的方法,主要有如下3种:二氧化碳与环状缩酮反应,二氧化碳与1,2-二醇及其衍生物反应,二氧化碳与环氧化物反应。围绕研发高活性的催化体系加以重点介绍。

The synthetic pathways of cyclic carbonates starting from carbon dioxide during recent years, such as the reaction of ketal and CO2, the reaction of 1, 2-diols and CO2, and the cycloaddition between epoixde and CO2, were summarized, especially focusing on development of highly eff/cient catalyst systems for the reaction.