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NO_2在NaCl表面的非均相反应 被引量：3

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摘要 采用新的样品制备方法和气-固自由扩散的实验方式,使用漫反射傅立叶转换红外光谱原位反应器,结合离子色谱、X-射线光电子能谱、扫描电子显微镜等分析方法,研究了NO2在NaCl表面的非均相反应.研究表明反应不只是发生在颗粒物表面,体相也参与了反应;颗粒物表面的活性点对反应起决定作用,同时测定了反应级数为二级,反应摄取系数为(1.54±0.70)×10?5.
作者 李宏军 朱彤 丁杰 陈琦 徐冰烨
机构地区 北京大学环境学院环境模拟与污染控制国家重点实验室
出处 《中国科学（B辑）》 CSCD 北大核心 2005年第6期506-512,共7页 Science in China(Series B)
基金 国家重点基础研究发展规划(973)(2002CB410802) 国家自然科学基金(批准号:20077001) 教育部重点项目资助
关键词 DRIFTS 气-固扩散 非均相反应 反应级数 反应摄取系数
分类号 O643.1 [理学—物理化学]
  • 相关文献

参考文献21

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二级参考文献17

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共引文献87

同被引文献46

  • 1王磊,王磊,黄丹曦,王旭东.高岭土对不同污染物微滤过程的影响[J].环境工程学报,2015,9(4):1747-1751. 被引量：2
  • 2刘咸德,董树屏,李冰,高占君,李玉武,MOON Kil-Choo,GHIM Young Sung.沙尘暴事件中大气颗粒物化学组分的浓度变化和硫酸盐的形成[J].环境科学研究,2005,18(6):12-17. 被引量：22
  • 3杜林,徐永福,葛茂发,贾龙,王庚辰,王殿勋.烟雾箱模拟乙炔和NO_x的大气光化学反应[J].环境科学,2007,28(3):482-488. 被引量：14
  • 4Usher C R,Michel A E,Grassian V H,Reactions on Mineral Dust.Chemical Reviews,2003,103(12):4883-4939
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  • 7Borensen C,Kirchner U,Scheer V et al.,Mechanism and Kinetics of the Reactions of NO2 or HNO3 with Alumina as a Mineral Dust Mmodel Compound.Journal of Physical Chemistry A,2000,104(21):5036-5045
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  • 10Goodman A L,Heterogeneous Uptake of Sulfur Dioxide on Aluminum and Magnesium Oxide Particles.Journal of Physical Chemistry A,2001,105(25):6109-6120

引证文献3

二级引证文献13

中国科学（B辑）
2005年 第6期

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