摘要
The title compound, C24H28ClCuN4O6 （Mr = 567.49）, has been prepared and its crystal structure has been determined by X-ray diffraction method. The crystal belongs to monoclinic, space group C2/c with a = 23.1905（14）, b = 30.1877（12）, c = 7.4881 （3） A, β = 97.631 （2）°, V = 5195.8（4） A^3, Z = 8, Dc = 1.451 g/cm^3,μ = 0.989 mm^-1, F（000） = 2352, S = 1.030, R = 0.0694, wR = 0.2120 （I 〉 2σ（I））, R = 0.0950 and wR = 0.2322 （all data）. The crystal consists of the Cu（Ⅰ） complex and lattice water molecules. The Cu（Ⅰ） atom is coordinated by two phenanthroline （phen） molecules and one chlorine anion with a distortetl trigonal dipyramidal coordination geometry. By the aid of aromatic π-π stacking, the Cu（Ⅰ） complex molecules form two-dimensional supramolecular layers. Lattice water molecules locate between the adjacent layers to form a three-dimensional sandwich-like supramolecular structure.
The title compound, C24H28ClCuN4O6 （Mr = 567.49）, has been prepared and its crystal structure has been determined by X-ray diffraction method. The crystal belongs to monoclinic, space group C2/c with a = 23.1905（14）, b = 30.1877（12）, c = 7.4881 （3） A, β = 97.631 （2）°, V = 5195.8（4） A^3, Z = 8, Dc = 1.451 g/cm^3,μ = 0.989 mm^-1, F（000） = 2352, S = 1.030, R = 0.0694, wR = 0.2120 （I 〉 2σ（I））, R = 0.0950 and wR = 0.2322 （all data）. The crystal consists of the Cu（Ⅰ） complex and lattice water molecules. The Cu（Ⅰ） atom is coordinated by two phenanthroline （phen） molecules and one chlorine anion with a distortetl trigonal dipyramidal coordination geometry. By the aid of aromatic π-π stacking, the Cu（Ⅰ） complex molecules form two-dimensional supramolecular layers. Lattice water molecules locate between the adjacent layers to form a three-dimensional sandwich-like supramolecular structure.
基金
ThismaterialwasbaseduponworkfundedbyZhejiangProvincialNaturalScienceFoundationofChina(No.R203154)
