摘要
A novel coordination polymer [Co3（tma）（pda）2（H2O）3]n·nH2O was synthesized by hydrothermal reaction of 3-（3-pyridyl）acrylate acid （pda） and trimesic acid （tma） with COCl2·6H2O. The structure was characterized by elemental analysis, IR spectroscopy and X-ray single-crystal diffraction analysis. It crystallizes in triclinic, space group PT with a = 9.569（4）, b = 12.562（6）, c = 12.666（6） A, a = 97.321（7）, β = 110.295（7）, γ = 106.110（7）°, V = 1328.9（10）A^3, Dc = 1.877 g/cm^3, Mr = 751.24, Z = 2,μ = 1.930 mm^-1, F（000） = 758, the final R = 0.0392 and wR = 0.0837. The diffraction result shows that Co atoms are linked through pda and tma ligands to form an infinite three-dimensional network.
A novel coordination polymer [Co3（tma）（pda）2（H2O）3]n·nH2O was synthesized by hydrothermal reaction of 3-（3-pyridyl）acrylate acid （pda） and trimesic acid （tma） with COCl2·6H2O. The structure was characterized by elemental analysis, IR spectroscopy and X-ray single-crystal diffraction analysis. It crystallizes in triclinic, space group PT with a = 9.569（4）, b = 12.562（6）, c = 12.666（6） A, a = 97.321（7）, β = 110.295（7）, γ = 106.110（7）°, V = 1328.9（10）A^3, Dc = 1.877 g/cm^3, Mr = 751.24, Z = 2,μ = 1.930 mm^-1, F（000） = 758, the final R = 0.0392 and wR = 0.0837. The diffraction result shows that Co atoms are linked through pda and tma ligands to form an infinite three-dimensional network.
基金
ThisworkwassupportedbytheNaturalScienceFoundationofHebeiprovince(B2005000534)
