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Crystal Structure and Spectrum Character of Bis[1-(4-Methoxyphenyl)-3-(1H-1,2,4-Triazol-1-yl)-1-Propanone] dichorozinc(Ⅱ) Complex

Crystal Structure and Spectrum Character of Bis[1-(4-Methoxyphenyl)-3-(1H-1,2,4-Triazol-1-yl)-1-Propanone] dichorozinc(Ⅱ) Complex
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摘要 The titled new complex was synthesized and determined by X-ray diffraction. The crystal belongs to monoclinic, P-I group, a=1.8997(4)nm, b-0.581 07(12)nm, c=2.4209(5)nm, β-90.65(3)°, V=2.672 2(9) nm^3, Z=4, Dc= 1.488 g/cm^3, It has C2 symmetry with the axis through the Zn atom, and the zinc atom is coordinated by two N atoms of the 1-(4-methoxyphenyl) 3-( 1H-1, 2, 4-triazol-1-yl)-1-propanone ligands and two C1^- atoms, forming a slightly distorted tetrahedron. Intermolecular hydrogen bonds make the complex stable. IR and electronic spectra study of the target complex were also carried. The titled new complex was synthesized and determined by X-ray diffraction. The crystal belongs to monoclinic, P-I group, a=1.8997(4)nm, b-0.581 07(12)nm, c=2.4209(5)nm, β-90.65(3)°, V=2.672 2(9) nm^3, Z=4, Dc= 1.488 g/cm^3, It has C2 symmetry with the axis through the Zn atom, and the zinc atom is coordinated by two N atoms of the 1-(4-methoxyphenyl) 3-( 1H-1, 2, 4-triazol-1-yl)-1-propanone ligands and two C1^- atoms, forming a slightly distorted tetrahedron. Intermolecular hydrogen bonds make the complex stable. IR and electronic spectra study of the target complex were also carried.
出处 《Journal of Beijing Institute of Technology》 EI CAS 2005年第4期425-428,共4页 北京理工大学学报(英文版)
基金 SponsoredbytheNaturalScienceFoundationofHebeiProvince(205403)
关键词 1H-1 2 4-triazol-1-yl COMPLEX crystal structure UV-vis spectrum 1H-1,2,4-triazol-1-yl complex crystal structure UV-vis spectrum
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  • 1Han G D,Zhao S W,Li S W.Handbook of organic syn- thesis chemistry[]..1980
  • 2Clark R W,Squattrito P J,Sen A K,et al.Structural trendsin a series of divalent transition metal triazole com- plexes[].Inorganica Chi mica Acta.1999
  • 3Zhu D R,Xu Y,Mei Y H,et al.Crystal and molecular structure of a novel complex [ Mn( MOBPT) ( H2O)2 ( NCS)2] ( MOBPT =4-( p-methoxyphenyl )-3 ,5-bis (pyridin-2-yl)-1 ,2 ,4-triazole)[].Journal of Molecular Biology.2001
  • 4Demirayak S,Benkli K,Gven K.Synthesis of some3-arylamino-5-aryloxymethyl[1 ,2 ,4] triazole derivatives and their anti microbial activity[].Pharmaceutica Acta Helvetiae.1998
  • 5Menegola E,Broccia ML,Renzo F D,et al.Antifungal triazoles induce malformations in vitro[].Reproductive Toxicology.2001
  • 6Bei F L,Jian F F,Yang X J,et al.Bis(2-benzyl-1H- benzi midazole-N3)-dichlorozinc[].Acta Crystallographica.2000
  • 7Parvez M,Rusiewicz M.Bis(antazoline) dichlorozinc (Ⅱ)[].Acta Crystallographica.1995
  • 8Ng C H,Fun HK,Teo S B,et al.Bis(L-prolinato-N, O)zinc(Ⅱ)[].Acta Crystallographica.1995
  • 9Hartmann U,Vahrenkamp H.Zinc complexes of dipyridyl-triazoles[].Inorganica Chi mica Acta.1995
  • 10Pretsch E,Bhl mann P,Affolter C.Structure determi- nation of organic compounds : Tables of spectral data[]..2000

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