摘要
The titled new complex was synthesized and determined by X-ray diffraction. The crystal belongs to monoclinic, P-I group, a=1.8997(4)nm, b-0.581 07(12)nm, c=2.4209(5)nm, β-90.65(3)°, V=2.672 2(9) nm^3, Z=4, Dc= 1.488 g/cm^3, It has C2 symmetry with the axis through the Zn atom, and the zinc atom is coordinated by two N atoms of the 1-(4-methoxyphenyl) 3-( 1H-1, 2, 4-triazol-1-yl)-1-propanone ligands and two C1^- atoms, forming a slightly distorted tetrahedron. Intermolecular hydrogen bonds make the complex stable. IR and electronic spectra study of the target complex were also carried.
The titled new complex was synthesized and determined by X-ray diffraction. The crystal belongs to monoclinic, P-I group, a=1.8997(4)nm, b-0.581 07(12)nm, c=2.4209(5)nm, β-90.65(3)°, V=2.672 2(9) nm^3, Z=4, Dc= 1.488 g/cm^3, It has C2 symmetry with the axis through the Zn atom, and the zinc atom is coordinated by two N atoms of the 1-(4-methoxyphenyl) 3-( 1H-1, 2, 4-triazol-1-yl)-1-propanone ligands and two C1^- atoms, forming a slightly distorted tetrahedron. Intermolecular hydrogen bonds make the complex stable. IR and electronic spectra study of the target complex were also carried.
基金
SponsoredbytheNaturalScienceFoundationofHebeiProvince(205403)