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Several Rules for Treating Phenol Wastewater via Oxidation by O_3/UV-formed Radicals 被引量:2

Several Rules for Treating Phenol Wastewater via Oxidation by O_3/UV-formed Radicals
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摘要 The treatment of phenol wastewater with an ultraviolet source and an oxone generator by introducing salicylic acid as the capturer is described. The presence of HO during the phenol degradation has been proved. The impacts of factors such as acidity and reaction time on the HO formation are also discussed. The results demonstrate that HO ' generated from ozone/UV oxidation under a basic condition is the immediate cause of phenol degradation. At room temperature and a pH value of 9. 93, the degradation of phenol occurs rapidly within 0. 5 rain and the removal of phe- nol( 100 mg/L) is above 98. 5% within 15 min; in the meantime, the pH value declines gradually with the degradation of phenol. A discussion about the formation and the transformation of the intermediate products during phenol degradation is included. The treatment of phenol wastewater with an ultraviolet source and an oxone generator by introducing salicylic acid as the capturer is described. The presence of HO during the phenol degradation has been proved. The impacts of factors such as acidity and reaction time on the HO formation are also discussed. The results demonstrate that HO ' generated from ozone/UV oxidation under a basic condition is the immediate cause of phenol degradation. At room temperature and a pH value of 9. 93, the degradation of phenol occurs rapidly within 0. 5 rain and the removal of phe- nol( 100 mg/L) is above 98. 5% within 15 min; in the meantime, the pH value declines gradually with the degradation of phenol. A discussion about the formation and the transformation of the intermediate products during phenol degradation is included.
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2006年第1期25-28,共4页 高等学校化学研究(英文版)
基金 Supportedby985ProjectofJilinUniversity.
关键词 OZONE UV oxidation RADICAL Phenol wastewater Degradation Ozone UV oxidation Radical Phenol wastewater Degradation
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