固体碱催化剂在催化反应中的应用进展

Progress on Application of Solid Base Catalysts in Catalytic Reactions

概述了固体碱催化剂在催化反应中应用的最新进展,总结了近年来固体碱催化剂在(1)双键异构化反应;(2)氧化反应;(3)还原反应;(4)酯交换反应;(5)A ldol缩合、M ichael加成、Knoevenagel缩合、甲苯的甲醇侧链烷基化等C—C键的形成反应;(6)C—S i,C—O,C—P等碳杂键的形成等催化反应中的最新应用进展,并指出了目前固体碱催化剂应用中存在的问题。

Progress on application of solid base catalysts in catalytic reactions was reviewed. Solid base catalysts were classified according to their functions. The newest applications of solid base catalysts were reviewed, namely （ 1 ） double bond isomerization of alkenes and alkynes, （ 2 ） oxidation, （ 3 ） reduction, （ 4 ） transesterification, （ 5 ） formation of C-C bond with Aldol condensation, Michael addition, Knoevenagel condensation, side - chain alkylation of toluene, （ 6 ） formation of C-Si, C O and C-P bonds. Problems to be solved in solid base catalysts and future development were also discussed.