摘要
A TiO2 modified with PtⅣ chloride was investigated by diffuse reflectance UV-Vis spectra（DRS）,X-ray photoelectron spectroscopy（XPS）, surface photovoltage spectroscopy（SPS） and electric field-induced surface photovoltage spectroscopy（EFISPS）.XPS showed that a Ti-O-PtⅣClx surface complex between PtⅣ chloride and TiO2 appears to be responsible for visible light absorption.An electron transfer from the surface-complexed PtⅣClx to the conduction band of TiO2 upon absorbing visible light was confirmed by SPS and EFISPS.
A TiO2 modified with Pt^Ⅳ chloride was investigated by diffuse reflectance UV-Vis spectra （ DRS）, X-ray photoelectron spectroscopy （XPS）, surface photovohage spectroscopy（SPS） and electric field-indueod surface photovoltage spectroscopy（EFISPS）. XPS showed that a Ti-O-Pt^Ⅳ Clx surface complex between Pt^Ⅳ chloride and TiO2 appears to be responsible for visible light absorption. An electron transfer from the surfaceeomplexod Pt^Ⅳ Clx to the conduction band of TiO2 upon absorbing visible light was confirmed by SPS and EFISPS.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2006年第2期340-342,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金(批准号:20133010
20473018
20273014)
教育部科技重点项目(批准号:03061)
福建省自然科学基金重大项目(批准号:2003F004)
福建省教育厅重点项目(批准号:JA02138)
国家重大基础研究前期专项基金(批准号:2004CCA07100)资助
