非对映选择醛酮催化氰化加成反应催化剂的发展及机理

Application of catalysts and mechanism of the diastereoselective cyanation addition of aldehydes and ketones

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摘要综述了非对映选择醛酮催化氰化加成反应催化剂的发展并提出了可能的机理解释。 Cyanation addition of aldehydes and ketones is an important reaction in asymmetric addition. This article reviews the recent advance about the, application of catalysts and reasonable mechanism explanations in the reaction of diastereoselective cyanation addition of aldehydes and ketones.

作者王晓丽王艳学边占喜

机构地区内蒙古师范大学化学与环境科学学院内蒙古大学化学化工学院

出处《化学试剂》 CAS CSCD 北大核心 2006年第1期23-26,共4页 Chemical Reagents

基金国家自然科学基金(20062004)资助项目内蒙古师范大学青年基金(QN00102)资助项目

关键词醛酮催化氰化加成反应非对映选择性机理 catalyst cyanation of aldehydes and ketones diastereoselective mechanism

分类号 O623.54 [理学—有机化学]

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1Gregory R J H. Cyanohydrins in nature and the laboratory:Biology preparations, and synthetic applications [ J ]. Chem.Rev., 1999,99(12) :3649-3682.
2Evans D A, Treadle L K, Carroll G L. Cyanosilylation of aldehydes and ketones. A convenient route to cyanohydrin derivatives. [ J ] . J. Chem. S . Chem. Commun . , 1973 : 55-56.
3Evans D A, Carroll G L, Truesdale L K. Synthetic application of trimethylsilyl cyanide. An Efficient synthesis of β-aminomethyl alcohols[J]. J. Org. Chem., 1974,39(7) :914-917.
4Evans D A, Truesdale L K. Carbonyl insertion reaction of silicon pseudohalides : Catalysis [ J ]. Tetrahedron Left. , 1973,14(49) : 4929-4932.
5Rasmussen J K, Heilmann S M. A facile, one-pot synthesis of silylated cyanohydrins[ J ]. Synthesis, 1978, (3) : 219-221.
6Failer J W, Gundersen L L. [ HC ( Py )3W ( NO )2 ( CO ) ](SbF6)2 as a Lewis acid precursor in additions of silylated C-nucleophiles to carbonyl compounds [ J ]. Tetrahedron Lett.,1993,34(14) :2275-2278.
7Reetz M T, Fox D N A. Carbon-carbon bond formation catalyzed by lithium perchlorate in dichloromethane[J]. Tetrahedron Lett., 1993,34(7) : 1119-1122.
8Miura T, Masaki Y. Catalytic activity of tetracyanoethylene in the reaction of aldehydes, ketones and actals with silylated nucleophiles[ J]. Chem. Soc . Perkin. Trans. 1,1994, (13):1659-1660.
9Matthias S, Gregory C F. Tributyhin cyanide-catalyzed addition of triethylsilyl cyanide to aldehydes [ J ]. J. Org. Chem. , 1994,59(23) :7178-7179.
10Whitesell J K, Apodaca R. Trimethylsilylcyanation of aldehydes and ketones catalyzed by diorganontin dichlorides [ J ].Tetrahedron Lett. , 1996,37(15) :2525-2528.

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2Qing Fang CHENG,Xing You XU,Ming Yan WANG,Jun CHEW,Wei Xing MA,Xu Jie YANG.Enantioselective Pinacol Coupling of Aromatic Aldehydes Induced by Chiral Titanium Complexes[J].Chinese Chemical Letters,2006,17(7):887-890.
3钯卡宾参与的烯基芳烃轴手性化合物的合成[J].有机化学,2016,36(3):670-670.
4王攀登,阳年发,凌莹,李继超,曹靖.三苯甲基取代烯烃的环氧化研究[J].有机化学,2007,27(7):885-889.
5ZhiHuaMA,CongLIU,等.Diastereoselective α-Alkylation of β-Amino Esters: Preparation of Novel α-Substituted β-Amino Esters from α-Amino Acids[J].Chinese Chemical Letters,2002,13(8):721-724.
6谢生明,刘虹,杨江蓉,艾萍,袁黎明.单手螺旋三维骨架材料[{Cu(sala)}_n]混合全戊基-β-环糊精用于促进气相色谱对映选择分离[J].色谱,2016,34(1):113-118. 被引量：6
7WANG Ping,WANG Lei,WANG Li-cheng,LI Chun-yuan,WANG Ren,MIAO Qing-hua,YANG Ming,WANG Zhi.Rapid Estimation of Enantioselectivity in Lipase-catalyzed Resolution of Glycidyl Butyrate Using pH Indicator[J].Chemical Research in Chinese Universities,2009,25(1):72-75.
8董淑荣,尹承烈.用手性配体改性铝锂试剂对芳香酮的还原[J].合成化学,1999,7(3):226-228. 被引量：1
9刘军,王德先,郑企雨,王梅祥.Biocatalytic Synthesis of Highly Enantiopure 1,4-Benzodioxane-2-carboxylic Acid and Amide[J].Chinese Journal of Chemistry,2006,24(11):1665-1668.
10杨朝芬,杨俊,朱艳琴,孙晓东,李贤均,陈华.L-脯氨酸稳定的铱催化苯乙酮及其衍生物不对称加氢反应(英文)[J].物理化学学报,2011,27(12):2887-2892. 被引量：5

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非对映选择醛酮催化氰化加成反应催化剂的发展及机理

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