摘要本文研制出具有较强实用性的串联型微电极(MCCS,Microcells Connected in Series),并将其用于高价态药物链霉索的测定,测定灵敏度与准确度显著提高。依据正态分布函数的卷积原理,提出了MCCS电极的误差模型,修正了文献[1]的疏漏片面之处,用Monte Carlo实验进行了验证。
2R. Stepak. Application of cells connected in series as a means to enhance the sensitivity of potentiometric analysis[J] 1983,Fresenius’ Zeitschrift für Analytische Chemie(7):629~630
3A. Parczewski,R. St?pak. Random error in the CCS (cells connected in series) potentiometric method[J] 1983,Fresenius’ Zeitschrift für Analytische Chemie(1):29~31