薄层液/液界面电子转移动力学的研究进展

Progress in the Study of Electron Transfer Across Liquid/liquid Interfaces Using Thin Layer Method

薄层循环伏安法是研究液/液界面电荷转移的一种新方法,具有简单、快速、易操作的优点。文章回顾了液/液界面电化学的发展历史,介绍了薄层法的实验原理,对其在电化学中的应用和研究进展进行了评述,总结了界面驱动力与电子转移速率的关系。

Thin-layer cyclic voltammetry （TLCV） is a novel method for studying the charge transfer at liquid/liquid interface recently. It has many advantages such as simplicity, rapidity and convenience. The paper gives a brief introduction of the electrochemistry of electron transfer across liquid/liquid interfaces and its experiment principle using thin layer method. The application and progress of the thin layer method in the study of electron transfer across liquid/liquld interface is reviewed. In addition, the relationship between the driving force and the rate of electron transfer across the interface is summarized. 43 papers are cited.