摘要
薄层循环伏安法是研究液/液界面电荷转移的一种新方法,具有简单、快速、易操作的优点。文章回顾了液/液界面电化学的发展历史,介绍了薄层法的实验原理,对其在电化学中的应用和研究进展进行了评述,总结了界面驱动力与电子转移速率的关系。
Thin-layer cyclic voltammetry (TLCV) is a novel method for studying the charge transfer at liquid/liquid interface recently. It has many advantages such as simplicity, rapidity and convenience. The paper gives a brief introduction of the electrochemistry of electron transfer across liquid/liquid interfaces and its experiment principle using thin layer method. The application and progress of the thin layer method in the study of electron transfer across liquid/liquld interface is reviewed. In addition, the relationship between the driving force and the rate of electron transfer across the interface is summarized. 43 papers are cited.
出处
《分析化学》
SCIE
EI
CAS
CSCD
北大核心
2006年第1期135-139,共5页
Chinese Journal of Analytical Chemistry
基金
国家自然科学重点基金(No.20335030)
教育部第四届高校青年教师科研奖励计划基金(No.TRAPOYT)
甘肃省自然科学基金(No.3ZS051-A25-023)资助项目
关键词
液/液界面
薄层循环伏安法
界面电子转移
评述
Liquid/liquid interface, thin-layer cyclic voltammetry, electron transfer, review