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Kramers-Kronig变换对电化学体系的适用性 被引量:5

On the Validity of Kramers-Kronig Transform for the Electrochemical Systems
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摘要 从复变函数的解析性质讨论了Kramers—Kronig变换对电化学体系的阻纳的适用性.由于电化学体系并非总可视为线性.故Bode四条件不一定都能得到满足,文中提出检验电化学体系阻纳适用K-K变换所必须满足的三个必要充分条件,并讨论了各种不同的解析形式和等效电路对K-K关系的适用性. The validity of Kramers--Kronig transform for the electrochemical systems has been discussed on the basis of the analytic properties of the immittance as a function of complex variable. As electrochemical systems canno always be regarded as linear, Bode's four requirements have to be reconsidered.Three necessary and sufficient conditions are proposed to test the clectrochemical systems to see whether K -- K transform is valid for them.
作者 史美伦
出处 《同济大学学报(自然科学版)》 EI CAS CSCD 1996年第4期445-449,共5页 Journal of Tongji University:Natural Science
关键词 电化学 K-K变换 等效电路 Electrochemical impedance spectroscopy Kramers-Kronig trans form Equivalent circuits
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参考文献2

  • 1史美伦,同济大学学报,1994年,22卷,3期,346页
  • 2曹楚南,腐蚀电化学原理,1985年

同被引文献13

  • 1林成涛,王军平,陈全世.电动汽车SOC估计方法原理与应用[J].电池,2004,34(5):376-378. 被引量:197
  • 2史美伦,李通化,周国定.交流阻抗谱中的Kramers—Kronig关系及其应用[J].同济大学学报(自然科学版),1994,22(3):346-349. 被引量:2
  • 3John D G,Searson P C,Dawson J L. Use of AC impedance technique in studies on steel in concrete in immersed conditions[J]. Br Corros J, 1981,16(2): 102 - 106.
  • 4Macdonald D D, Urquidi-Macdonald M. Application of KramersKronig transforms to the analysis of electochemical impedance data.Ⅰ. Polarization resistance [J]. J Electrochem Soc, 1985, 132(11) :2316 -2319.
  • 5Urquidi-Macdonald M, Real S, Macdonald D D. Application of Kramers-Kronig transforms to the analysis of electrochemical impedance data. Ⅱ. Transformations in the complex plane[J ]. J Electrochem Soc, 1986,133(10) :2018 - 2024.
  • 6Shinh H, Mansfeld F. On the validity of Kramers-Kronig transforms in corrosion systems[J]. Corros Sci, 1988,28: 933 - 935.
  • 7SURESH P, SHUKLA A K, MUNICHANDRAIAH N. Temperature dependence studies of AC impedance of lithium-ion cells[J].Journal of Applied Electrochemistry, 2002,32: 267-273.
  • 8KEDDAM M, STOYNOV Z, TAKENOUTI H. Impedance measurement on Pb/H2SO4batteries[J].J Appl Electrochem,1977(7): 539.
  • 9ISAACSON M J,DAMAN M E.Hollands worth RP[C]//CAIRNS E J, MCLARNON F.Proceedings of the thirty second intersociety energy conversion engineering conference. New York:American Institute of Chemical Engineers, 1977:31.
  • 10史美伦,施弢.混凝土中钢筋锈蚀测量的交流导纳方法[J].腐蚀与防护,1997,18(3):23-25. 被引量:22

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