摘要
研究了八乙基卟啉钌(II)及四种带有不同取代基的四苯基卟啉羰基合钌(II)的电化学行为,考察了取代基对羰基钌卟啉的电化学性质的影响,测定了其电子转移反应速率常数。
The redox properties of four para- substituted tetraphenylporphyrin carbonyl complexes of ruthenium (Ⅱ) and earbonyl octakisethyl -porphyrinatoruthenium (Ⅱ) have been investigated using electrochemical technlques.The standant rate constants of electron transfer of the five compounds have been obtained and the effects of subsfituents on the electrode reactions of the five porphyrin carbonyl complexes of ruthenium (Ⅱ) have been disccussed.
出处
《宜春学院学报》
2005年第6期37-39,共3页
Journal of Yichun University
基金
湖北省自然科学基金项目(No.2005ABA021)
江西省自然科学基金项目(No.0520083)
关键词
钌卟啉
电化学
电子转移反应速率常数
nahenium (Ⅱ) porphyrin complexes
cyclic voltammetry
standard rate constants of electron transfer