软化学法合成有机杂化锗、锡硫属化物的研究进展

Recent Progress in Soft Chemical Synthesis of Organic Hybrid Chalcogenidogermanate and Chalcogenidostannate

本文总结了软化学方法合成有机杂化的锗、锡硫属化合物的研究进展,介绍了代表性物质的结构以及[M2Q6]4-、[M3Q7]2-、[M4Q9]2-、[M4Q10]4-(M=Ge,Sn;Q=S,Se,Te)等构筑单元的超分子组装、聚合过程中的主要影响因素。

This review briefly summarizes the recent progress in soft chemical synthesis of organic hybrid chalcogenidogermanate and chalcogenidostannate. The typical compound structures, soft chemical synthetic approaches and important factors affecting self-assembling and polymerizing of [M2Q6]^4-, [M3Q7]^2- , [M4Q9]^2- and [M4Q10]^4- （M=Ge, Sn; Q=S, Se, Te） building blocks are described.