摘要
The title complex of nickel (II) with 3,5-dimethylbenzoic acid, m-methylbenzoic acid and 1,10- phenanthroline was synthesized and characterized. Crystal data for this complex: triclinic, space group P1, a=1.198 5(2) nm, b=1.315 3(2) nm, c=1.531 8(3) nm, α=92.602(3)°, β=103.292(3)°, γ=114.849(3)°, V=2.104 7(6) nm3, Dc=1.361 g·cm-3, Z=2, F(000)=902, final GooF=1.071, R1=0.067 2, wR2=0.155 5. The crystal structure shows that the nickel ion is coordinated with four nitrogen atoms of two 1,10-phenanthroline molecules and two oxygen atoms of one 3,5-dimethyl benzoic acid molecule, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex was also investigated. CCDC: 286966.
The title complex of nickel （Ⅱ） with 3,5-dimethylbenzoic acid, m-methylbenzoic acid and 1,10- phenanthroline was synthesized and characterized. Crystal data for this complex： triclinic, space group P1^-, α= 1.1985（2） nm, b=1.315 3（2） nm, c=1.531 8（3） nm, α=92.602（3）°,β=103.292（3）°, T=114.849（3）°, V=2.104 7（6） nm^3, Do=1.361 g·cm^-3, Z=2, F（000）=902, final GooF=1.071, R1=0.067 2, ωR2=0.155 5. The crystal structure shows that the nickel ion is coordinated with four nitrogen atoms of two 1,10-phenanthroline molecules and two oxygen atoms of one 3,5-dimethyl benzoic acid molecule, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex was also investigated.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2006年第3期555-558,共4页
Chinese Journal of Inorganic Chemistry
基金
湖南省自然科学基金(No.05JJ30020)
湖南省科技厅科技开发基金(No.04GK3035)
衡阳师范学院青年基金(No.2003C16)资助。
关键词
镍(Ⅱ)
配合物
晶体结构
电化学性质
nickel（Ⅱ）
complex
crystal structure
electrochemical property
