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放电等离子烧结La_(0.67)Sr_(0.33)MnO_(3-δ)粉体的输运性质 被引量：1

TRANSPORT PROPERTIES OF La_(0.67)Sr_(0.33)MnO_(3-δ) POWDER BY SPARK PLASMA SINTERING
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摘要 用自蔓延高温合成技术合成La0.67Sr0.33MnO3-δ粉体。探讨了放电等离子烧结的烧结温度对合成粉体的显微结构和输运性质的影响。扫描电镜和密度测试结果表明:放电等离子烧结后的晶粒大小均匀,烧结体致密度高。随着烧结温度的升高,样品的电阻率明显下降。由于氧缺位的存在,金属绝缘相转变温度随着烧结温度的升高而降低。相对于传统的固相烧结,放电等离子工艺制得的样品的致密度较高导致颗粒间的巨磁电阻有所提高。 The powder of was synthesized by self-propagating high-temperature synthesis （SHS）. The influences of the sintering temperature of spark plasma sintering （SPS） on the microstructure and the transport properties of the powder are discussed. The results of scanning electron microscope and the density test show that the sample produced by SPS has high density and a uniform grain size. The transition temperature of the metal - insulator decreases with the increase of the sintering temperature due to the deficiency of oxygen. Compared to the conventional sintering, the elevated colossal magnetoresistance between grains can be attributed to the high density of the sample by SPS.
作者 雷丽文 傅正义 张金咏 王玉成
机构地区 武汉理工大学材料学院 武汉理工大学材料复合新技术国家重点实验室
出处 《硅酸盐学报》 EI CAS CSCD 北大核心 2006年第2期158-161,共4页 Journal of The Chinese Ceramic Society
基金 国家自然科学基金(50272047)资助项目
关键词 掺锶锰酸镧 放电等离子烧结 烧结温度 输运性质 自蔓延高温合成 strontium doped lanthanum manganite spark plasma sintering sintering temperature transport property selfpropagating high-temperature synthesis
分类号 TQ132 [化学工程—无机化工]
  • 相关文献

参考文献14

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二级参考文献9

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共引文献6

同被引文献21

  • 1李阿丹.La_(2/3)Ca_(1/3)Mn_((1-x))Fe_xO_3溶胶凝胶制备和表征[J].硅酸盐通报,2007,26(2):401-403. 被引量：2
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硅酸盐学报
2006年 第2期

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