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微波水热法合成新型CZBO晶体的研究 被引量:1

Study on CZBO Microcrystal by Microwave-hydrothermal Method
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摘要 本文报道了微波水热法生长晶体硼酸锌镉(CZBO)的研究,合成出新物质(Cd0.01Zn0.99)2BO3(OH)。用多晶XRD粉末衍射、元素分析、扫描电镜、红外光谱、热分析等多种手段对产物进行了表征。所得的CZBO微米级晶体呈长条状,其粉末倍频效应是KDP微晶的1.25倍。 A novel NLO microcrystal (Cd0.01 Zn0.99 )2BO3 (OH) was synthesized by microwavehydrothermal method. The reactions with different times were compared and the crystallized products were identified by X-ray powder diffraction, SEM, IR, ICP-AES,etc. ( Cd0.01Zn0.99 )2BO3 (OH) microcrystal showed a SHG coefficient with 1.25 times as large as that Of KDP crystal.
机构地区 清华大学化学系
出处 《人工晶体学报》 EI CAS CSCD 北大核心 2006年第1期15-19,共5页 Journal of Synthetic Crystals
基金 国家自然科学基金资助项目(No.50590402)
关键词 微波水热法 CZBO微晶 红外光谱 倍频系数 microwave-hydrothermal method CZBO microcrystal infrared spectrum SHG coefficient
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