摘要
采用与文献不同的路线合成了4,4′二(p甲基苯基)2,2′二联吡啶,与文献结果相比,总收率由4.0%提高至15.3%.该化合物和4,4′二羧基2,2′二联吡啶组成混合配体与金属钌配位,合成了两亲性、混配型配合物cisN,N4,4′二(p甲基)苯基2,2′二联吡啶N,N4,4′二羧基2,2′二联吡啶N,N二异硫氰钌配合物,并用IR,UVVis,NMR和MaldiTOF等手段进行表征.将该两亲性混配钌配合物首次用于对Hg2+的识别中,发现此配合物对Hg2+表现出灵敏的选择性“肉眼”识别:在DMF/乙醇溶液(体积比1∶9)中加入Hg2+后,MLCT态吸收由530nm蓝移到485nm.该配合物与Hg2+以1∶1(摩尔比)结合,检测限可低至0.5×10-6mol/L.
4,4'-Di (p-methylphenyl)-2,2'-bipyridine was synthesized via modified routine with a high yield of 15.3%, and was used as a ligand to form a new mixed-ligand amphiphilic ruthenium complex, cis-N,N-4 ,4'- di (p-methylphenyl)-2, 2'-bipyridine-N, N-4, g'-dicarboxy-2, 2'-bipyridine-N, N-dithiocyanato ruthenium ( H ). This new mixed-ligands amphiphilic ruthenium complex was characterized by IR, UV-Vis, ^1H NMR and Maldi-TOF MS spectra and firstly used to detect Hg^2+. Its MLCT absorption(530 nm) was blue-shifted to 485 nm when Hg^2+ was added to DMF-ethanol(volume ratio 1: 9) solution of the complex. The complex was combined quantitatively with Hg^2+ not with other metal cations by the molar ratio of 1 : 1, indicating that it can be used as a selective naked-eye sensor for Hg^2 +. Its detective limit is 0. 5×10^-6 mol/L.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2006年第3期419-423,共5页
Chemical Journal of Chinese Universities
基金
国家"八六三"计划(批准号:2002AA302403)
国家自然科学基金(批准号:20490210)
上海市科委基金(批准号:03QB14006
03DZ12031)资助.