水溶性有机物对草萘胺在土壤中吸附与迁移的影响

Effects of Dissolved Organic Matter on Napropamide Adsorption and Transport in Soil System

采用批次吸附试验和土柱淋洗试验,研究了绿肥和污泥中水溶性有机物(DOM)对除草剂草萘胺在黄棕壤和石灰性潮土上吸附和迁移影响.结果表明,供试DOM均能明显降低草萘胺在2种土壤上的吸附,促进草萘胺的迁移,在黄棕壤上效果更明显.在所研究的草萘胺和DOM浓度范围内,绿肥DOM(GM)都比污泥DOM(SS)作用显著.草萘胺的吸附等温线可用Freundlich方程定量描述.绿肥DOM和污泥DOM可分别使黄棕壤中草萘胺吸附量比对照处理(不加DOM)减少22.9%和11.3%,使迁移出土体的草萘胺总量提高了73.42%和26.87%,而使潮土中草萘胺的吸附量减少了9.5%和6.5%,迁移出土体的草萘胺总量增加了43.54%和28.29%.因此,农业土壤中溶解性有机物对农药环境行为有一定影响.

Dissolved organic matter （DOM） can affect the environmental behaviors of herbicides in soil. Batch adsorption and column experiments were conducted to measure the sorption and leaching of napropamide in soils in the presence of DOM derived from green manure （GM） and sewage sludge （S_q）. DOM reduced sorption of napropamide significantly onto the tested soils, consequently which facilitated the transport of napropamide exhibited by soil column experiment. The sorption inhibition and the increased mobility of napropamide caused by DOM of GM origin were more significant than that of SS origin for the same soil. Within the selected concentration range of the napropamide and DOM in this study napropamide sorption isotherm could be described well by the Freundllch equation. In comparison with the control, DOM of GM and SS origins could reduce napropamide adsorption by 22.9 % and 11.3 % in the yellow brown soil and 9.5 % and 6.5 % in the calcareous soil, respectively. Correspondingly, in the presence of DOM the leaching losses of napropamide in soil column increased by 73.42 % and 26.87 % in the yellow-brown soil and 43.54 % and 28.29 % in the calcareous soil, respectively.