摘要
The title compound （C15H19FeNO2S, Mr = 333.22） was synthesized by the reaction of ferrocenesulfonyl chloride with hexahydropyridine, and characterized by ^1H NMR, IR and elemental analysis. The crystal belongs to monoclinic, space group P21/n with a = 6.0472（5）, b = 20.4897（6）, c = 11.6584（8）A°,β = 91.3120（10）°, V = 1444.16（16） A°^3, Z = 4, Dc= 1.533 g/cm^3, F（000） = 696,μ = 1.188 mm^-1, the final R = 0.0309 and wR = 0.0736 for 2057 observed reflection with I 〉 2σ（I）. The structure analysis demonstrates that two cyclopentadienyl rings are almost parallel with a dihedral angle of 1.70°, and hexahydropyridine moiety exists in a chair conformation. Bioassay indicates that the title compound has a good fungicidal activity.
The title compound （C15H19FeNO2S, Mr = 333.22） was synthesized by the reaction of ferrocenesulfonyl chloride with hexahydropyridine, and characterized by ^1H NMR, IR and elemental analysis. The crystal belongs to monoclinic, space group P21/n with a = 6.0472（5）, b = 20.4897（6）, c = 11.6584（8）A°,β = 91.3120（10）°, V = 1444.16（16） A°^3, Z = 4, Dc= 1.533 g/cm^3, F（000） = 696,μ = 1.188 mm^-1, the final R = 0.0309 and wR = 0.0736 for 2057 observed reflection with I 〉 2σ（I）. The structure analysis demonstrates that two cyclopentadienyl rings are almost parallel with a dihedral angle of 1.70°, and hexahydropyridine moiety exists in a chair conformation. Bioassay indicates that the title compound has a good fungicidal activity.
