摘要
A novel nickel（Ⅱ） complex Ni（C6H7N）2（SCN）2（H2O）2 （C14H18N4NiO2S2, Mr= 397.15） has been synthesized and structurally characterized by X-ray analysis. The crystal is of monoclinic, space group P21/c with a = 9.212（2）, b = 13.132（3）, c = 7.8794（19） A°, β = 99.142（3）°, Z = 2, V = 41.1（4） A°^3 Dc= 1.402 g/m^3, μ（MoKα） = 1.264 mm^-1, F（000） = 412, R1 = 0.0303 and wR2= 0.0794 for 1387 observed reflections （I 〉 2σ（I））. The title complex shows a 2-D network structure extended by twelve-membered Ni2O2H2S2C2N2 ring and ten-membered NiO2H3S2CN ring.
A novel nickel（Ⅱ） complex Ni（C6H7N）2（SCN）2（H2O）2 （C14H18N4NiO2S2, Mr= 397.15） has been synthesized and structurally characterized by X-ray analysis. The crystal is of monoclinic, space group P21/c with a = 9.212（2）, b = 13.132（3）, c = 7.8794（19） A°, β = 99.142（3）°, Z = 2, V = 41.1（4） A°^3 Dc= 1.402 g/m^3, μ（MoKα） = 1.264 mm^-1, F（000） = 412, R1 = 0.0303 and wR2= 0.0794 for 1387 observed reflections （I 〉 2σ（I））. The title complex shows a 2-D network structure extended by twelve-membered Ni2O2H2S2C2N2 ring and ten-membered NiO2H3S2CN ring.
