摘要
本文合成了一种新型巯基尾式锰（Ⅲ）卟啉，中位-[邻-（3-巯基苯甲酰胺基）苯基）三苯基卟啉合锰（Ⅲ）（简称Mn（Ⅱ）（m3phsH）．用紫外可见光谱、红外光谱进行了表征，并用分光光度法研究了中心离子分别为二价和三价时Mn（m3phsH）与CO、NO等双原子小分子的轴向配位性质。
A new tailed mangane porphrin complex, Mn(Ⅲ) (m3phsH),was synthesised and characterized by UV and IR spectrum. The axial coordinatire characteristics of both manganese (Ⅲ) and manganese(Ⅱ) complex with diatomic molecules CO, NO was studied by spectroscopic methed.
关键词
锰
卟啉
轴向
锰配合物
光谱
manganese, porphyrin, synthesis, axial
