二乙基二硫代氨基甲酸铁的溶剂热合成、晶体结构及电化学性质

Solventthermal Synthesis,Crystal Structure and Electrochemical Property of Iron Diethyldithiocarbamate Complex

溶剂热法合成了二乙基二硫代氨基甲酸铁配合物[(C5H10NS2)3Fe(III)],并用X射线衍射法测定了其晶体结构。该化合物属于单斜晶系,C2/c空间群,晶胞参数为a=1.425 2(3)nm,b=1.039 5(2)nm,c=1.719 2(3)nm,z=4,Dc=1.404 g.cm-3,μ=1.170 mm-1,F(000)=1 052,最终结构偏离因子R=0.049 1,wR=0.121 7,S=1.036。循环伏安研究表明该化合物具有电化学活性。

The title compound E（C5H10NS2）3Fe（Ⅲ）] was synthesized by solventthermal method and its structure was determined by single crystal X-ray diffraction. The compound crystallizes in monoclinic crystal system, space group C2/c with a = 1. 425 2 （2） nm,b=1. 039 5（2） nm,c=1. 719 2（3） nm, z=4,Dc=1. 404 g·cm^-3 ,μ=1. 170 mm^-1, F（000） = 1 052. The final R=0. 0491 and wR=0. 121 7 for 2 172 observed reflection [I2〉2σ（I） ]. The electrochemical property of the complex was also investigated.