摘要
合成了2种未见文献报道的9′-丙烯酰氧基吲哚啉螺萘并噁嗪衍生物(Ⅲa、Ⅲb),通过核磁共振氢谱、红外光谱确认了其结构.研究了在Zn(Ⅱ)螯合情况下,Ⅲa的紫外-可见吸收光谱,Zn(Ⅱ)螯合可以明显提高其开环体的热稳定性.
Two 9'-acryloxyindolinospironaphthoxazine derivatives( Ⅲa, Ⅲb) were synthesized and their structures were identified by ^1H NMR and IR. The UV-Vis spectroscopy of ma was studied with the formation of complex of Zn(Ⅱ ), which shows the complexation leads to a significant stabilization of the open form.
出处
《化学研究》
CAS
2006年第1期38-40,共3页
Chemical Research
基金
甘肃省高分子材料重点实验室基金和西北师范大学A级重点学科基金资助项目