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杯芳烃酰胺类衍生物对金属离子的萃取性能 被引量：4

Selective Extraction of Calix[n]arenes Amide Derivatives to Metal Ions
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摘要 以吗啉和六氢吡啶修饰的四种对叔丁基杯[n]芳烃酰胺类衍生物(n=6,8)为萃取试剂,研究了它们对Na+,K+及部分过渡金属等十种金属离子的萃取作用.结果表明此类杯芳烃酰胺类衍生物对过渡金属离子有良好的选择性识别作用.其中,吗啉取代基修饰的杯[8]芳烃萃取效果最好. The extracting properties of p-tert-butylcalix[ n] arene amide derivatives （ n = 6, 8） modified at the lower rim with morpholine or pyridine groups for Na^ ＋, K ^＋ and some transition metal cations were studied with atomic absorption methods. The primary results showed that the calix[ 8] arene amide bearing morphine group has best extraction capabilities.
作者 安琳 颜朝国
机构地区 徐州医学院药学系 扬州大学化学化工学院
出处 《化学研究》 CAS 2006年第1期86-88,共3页 Chemical Research
关键词 杯芳烃 酰胺 萃取 离子识别 原子吸收 calixarenes amide extraction metal ion recognition atomic absorption
分类号 O622.6 [理学—有机化学]
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参考文献11

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二级参考文献41

  • 1Asfari, Z.; Bohmer, V.; Harrowfield, J. M.; Vicens, J. Calixarenes, Kluwer, New York, 2001.
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共引文献36

同被引文献49

引证文献4

二级引证文献14

化学研究
2006年 第1期

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