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新型杯[4]芳烃醚的合成及其酯交换反应研究

Synthesis of calix[4]resorcinarenes ether derivative and its transesterification
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摘要 以正丁醛杯[4]芳烃母体化合物1与溴乙酸乙酯反应,得到杯[4]芳烃醚2,再与9-蒽甲醇进行酯交换反应,得到目标化合物3。对化合物2和目标化合物3的结构进行了熔点、红外光谱、核磁共振谱的表征。 The calix[4] resorcinarenes ether derivative 2 was syn-thesized from compound 1 and ethyl bromoacetate, and the transesterification reaction with calix[4] resorcinarenes ether derivative 2 and 9-anthracenmethanol produced the new compound 3. The new compound is characterized by IR and ^1HNMR.
出处 《化学试剂》 CAS CSCD 北大核心 2006年第3期167-168,184,共3页 Chemical Reagents
关键词 芳烃母体 9-蒽甲醇 合成 正丁醛 酯交换 calix [4] arene fluorescent residues 9-anthracenmethanol synthesis transesterification
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  • 1艾小红,陈忆新,杨世柱.带荧光基团蒽和芘的杯芳烃衍生物合成进展[J].广州大学学报(自然科学版),2005,4(2):122-128. 被引量:9
  • 2王键吉,刘文彬,卓克垒,卢锦梭.杯芳烃应用研究的新进展[J].化学通报,1996(2):11-17. 被引量:12
  • 3周科衍 吴俊民 等.有机化学实验[M].北京:高等教育出版社,1995..
  • 4[2] Takashi Jin, et al. Synthesis and optical resolution of a fluorescent chiral calix[4]arene with two pyrene moieties forming an intramolecular excimer[J]. Chem Commun, 1998, 1357.
  • 5[3] Fuangfa Unob, et al. An anthracene-based fluoresent sensor for transition ions derived from calix[4] arene[J]. Tetrahedron Lett, 1998, 39, 2951.
  • 6[4] Harris stephen J. Preparation of calixarene-based compounds having antibacterial, antifungal, anticancer, and anti-HIV activity. PCT INT. Appl. WO 95 19,974 (cl.C07D313/00),27 Jul 1995, IE Appl. 57, 24 Jan 1994; 148 pp(Eng)
  • 7[5] John R.Fransen, et al. Cation binding and conformation of octafunctionalized calix[4] resorcinarenes[J]. Can J Chem, 1995, 73, 2217.
  • 8[6] Izuo Aoki,et al. Molecular design of calix[4] arene-based fluorescent hosts[J]. Tetrahedron Lett, 1992, 33(1), 89.
  • 9[7] Izuo Aoki, et al. A new metal sensory system based on intramolecular fluorescence quenching on the ionophoric calix[4] arene ring[J]. J Chem Soc, Chem Commun, 1992, 730.
  • 10[8] Linda M, et al. Host-guest complexation. 48. octol building blocks for Kcavitands and carcerands[J]. J Org Chem, 1989, 54:1305.

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