摘要
使用分光光度法在近中性介质中对ＨＯＢｒ氧化葡萄糖的反应动力学进行了研究．结果表明，该反应对葡萄糖和ＨＯＢｒ都是一级，反应有负盐效应，并随Ｂｒ－浓度的增加，反应速度减慢．本文还提出了可能的反应机理．
The kinetics study of the oxidation of glucose with hydro bromic acid has been carried out in nearly neutral medium,by using spectrometry technique. It is a first order reaction for the glucose and the HOBr,This reaction has regative salt effect,and the reaction rate decreased with the increase of the concentration of Br-.According to the experimental facts and the reference literature,a possible reaction mechanism has been suggested,which can explain the experimental facts. The apparent activation parameters are also evaluated.
出处
《杭州大学学报（自然科学版）》
CSCD
1996年第2期168-171,共4页
Journal of Hangzhou University Natural Science Edition
基金
浙江省自然科学基金
关键词
分光光度法
次溴酸
葡萄糖
反应动力学
spectrometry
kinetics and mechanism
glucose
hydro bromic acid
