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聚芴(PFs)制备和表征的研究进展

Recent progress in polyfluorenes:preparation and characterization
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摘要 聚芴是一种重要共轭高分子材料,文章概述了可溶解性聚芴(或芴的寡聚物)的3种典型聚合方法,即FeCl3(三氯化铁)氧化法、镍催化法以及铂催化法合成聚芴,并按照分子链序列结构(交替共聚,嵌段工具,无轨共聚)的线索回顾了芴的共聚物的制备,简单介绍了目标产物的性质特征和对聚芴发光特性的影响。 Polyfluorenes are an important conjugated polymer with the property of semiconductors. In this paper, the synthesis routes of soluble polyfluorenes, namely-oxidation by FeCl3, Nickel（0） -catalyzed polymerization（Yamamoto coupling）, and Suzuki coupling Rolymerization, have been reviewed. The sequence structure（random, block and alternative copolymerization） in the main-chain of polyfluorenes is applied as the clue to review the progress of copolymers containing the units of the fluorene.
作者 王峰 童彬
机构地区 安徽建筑工业学院材料科学与工程系
出处 《合肥工业大学学报（自然科学版）》 CAS CSCD 北大核心 2006年第3期267-271,共5页 Journal of Hefei University of Technology：Natural Science
基金 安徽省自然科学基金资助项目(05021022)
关键词 聚芴 氧化法 镍催化法 铂催化法 polyfluorene oxidation method Yamamoto coupling Suzuki coupling
分类号 TQ314.2 [化学工程—高聚物工业]
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参考文献37

  • 1Ohmori Y,Uchida M,Muro K,et al.Blue electroluminescent diodes utilizing poly(alkylfluorene)[J].Jpn J Appl Phys,1991,30:L1941.
  • 2Pei Q,Yang Y.Efficient photoluminescence and electroluminescence from a soluble polyfluorene[J].J Am Chem Soc,1996,118(31):7 416-7 419.
  • 3Kreyenschmidt M,Klaerner G,Fuhrer T.Thermally stable blue-light-emitting copolymers of poly (alkylfluorene)[J].Macromolecules,1998,31(4):1 099-1 104,
  • 4Gaylord B S,Heeger A J,Bazan G C.DNA hybridization detection with water-soluble conjugated polymers and chromophore-labeled single-stranded DNA[J].J Am Chem Soc,2003,125 (4):896-900.
  • 5Liu B,Bazan G C.Homogeneous fluorescence-based DNA detection with water-soluble conjugated polymers[J].Chem Mater,2004,16 (23):4 467-4 470.
  • 6Belfield K D,Hagan D J,Schafer K J,et al.New twophoton absorbing fluorene derivatives:synthesis and nonlinear optical characterization[J].Organic Letter,1999,1(10):1 575-1 579.
  • 7Ravirajan P,Haque S A,Durrant J R.The effect of polymer optoelectronic properties on the performance of multilayer hybrid polymer/TiO2 solar cells[J].Adv Funct Mater,2005,15(4):609-614.
  • 8Hummelen J C,Svensson M,Zhang F,et al.High-performance polymer solar cells of an alternating polyfluorene copolymer and a fullerene derivative[J].Adv Mater,2005,15 (12):988-992.
  • 9He Y,Gong S,Hattori R,et al.High performance organ ic polymer light-emitting heterostructure devices[J].Appl Phys Lett,1999,74 (16):2 265-2 268.
  • 10Bernius M T,Inbasekaran M,OBrien J,et al.Progress with light-emitting polymers[J].Adv Mate,2000,12 (23):1 737-1 750,

二级参考文献16

  • 1徐敬柱,洪朝锽.芴的制备研究[J].浙江化工,1993,24(3):27-29. 被引量：3
  • 2[1]Niu Yuhua, Hou Qiong, Yuan Min, et al. Spectra adjustment and stability of electroluminescent devices based on random copolymers of fluorine and thiophene [J]. Chin. J. Lumin. (发光学报), 2002, 23(5):431-434 (in Chinese).
  • 3[2]Inbasekaran M, Woo E, Weishi Wu, et al. Interface formation between poly(9, 9-dioctylfluorene) and Ca electrode investigated using photoelectron spectroscopy [J]. Synthetic Metals, 2000, 397:111-112.
  • 4[3]Liu Bin, Yu Wanglin, Huang Wei. Synthesis, characterization, and structure-property relationship of novel fluorene-thiophene-based conjugated copolymers [J]. Macromolecules, 2000, 33:8945-8947.
  • 5[4]Lee J L, Klarner G, Davey M H, et al. Colorfast blue-light-emitting random copolymers derived from di-N-hexylfluorene and anthracene [J]. Adv. Mater., 1998, 10:993-996.
  • 6[5]Miyaura N, Yanagi T, Suzuki A. The palladium-catalyzed cross-coupling reaction of phenylboronic acid with haloarenes in the presence of bases [J]. Synth. Commun., 1981, 11(7):513-519.
  • 7[6]Martin A R, Yang Y. Palladium-catalyzed cross-coupling reactions of organoboronic acids with organic electrophiles [J]. Acta Chem. SCAND., 1993, 47:221-230.
  • 8[7]Johansson K, Andersson O, Olin A. New spectrofluorimetric reagent, 2, 3-diamino-1, 4-dibromonaphthalane, for the determination of selenium in biological materials [J]. Analyst, 1995, 120:423-429.
  • 9Kozlov V G, Parthasarathy G, Burrows P Z, et al. Optically pumped blue organic semiconductor lasers. J. Appl. Phys. Lett., 1998, 72(2): 114--146.
  • 10Liua B, Chenb Z K, Yub W, et al. Poly [9-methyl-9-(4-cyanobutyl)fluorene] synthesis towards water-soluble polyfluorenes. Thin Solid Films, 2002, 363 ( 1 - 2) :322 - 326.

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合肥工业大学学报（自然科学版）
2006年 第3期

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