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溶剂热法用粉体材料简单制备A_(2)S_(3)(A=Sb,Bi)亚微米/纳米线 被引量:1

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摘要 采用溶剂热法,用Sb2S3和Bi2S3粉体材料简单制备了A2S3(A=Sb,Bi)亚微米/纳米线.反应产物的形状和大小直接受反应温度、时间和溶剂的影响.使用乙二醇作溶剂得到的硫化锑棒要比使用乙二醇和乙二胺混合溶剂所制备的硫化锑线更粗且不均匀.在相同的反应条件下,使用乙二醇和乙二胺混合溶剂所制备的硫化铋亚微米线(平均直径150nm)比硫化锑的更细且更均匀.反应温度降低,得到硫化锑线所需要的反应时间更长.当反应温度和时间分别为200℃和24h时,能够得到平均直径在400nm左右的硫化锑亚微米线,但温度降到150℃,即便反应40h,也难制得全部的硫化锑线.讨论了从硫化锑粉体到硫化锑线的形成机理.
出处 《科学通报》 EI CAS CSCD 北大核心 2006年第5期519-523,共5页 Chinese Science Bulletin
基金 教育部留学归国基金 北京航空航天大学材料科学与工程学院优秀青年科研启动基金资助项目.
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  • 1Trentler T J,Hickman K M,Goel S C,et al.Solution-liquid-solid growth of crystalline Ⅲ-Ⅴ semiconductors:An analogy to vapor-liquid-solid growth.Science,1995,270(5243):1791~1794
  • 2Braun P V,Osenar P,Stupp S I.Semiconducting superlattices templated by molecular assemblies.Nature,1996,380(6572):325~328
  • 3Alivisatos A P.Semiconductor clusters,nanocrystals,and quantum dots.Science,1996,271(5251):933~937
  • 4Trentler T J,Goel S C,Hickman K M,et al.Solution-liquid-solid growth of indium phosphide fibers from organometallic precursors:Elucidation of molecular and nonmolecular components of the pathway.J Am Chem Soc,1997,119(9):2172~2181
  • 5Morales A M,Lieber C M.A laser ablation method for the synthesis of crystalline semiconductor nanowires.Science,1998,279(5348):208~211
  • 6Ye C H,Meng G W,Jiang Z,et al.Rational growth of Bi2S3 nanotubes from quasi-two-dimensional precursors.J Am Chem Soc,2002,124(51):15180~15181
  • 7George J,Radhakrishnan M K.Electrical conduction in Coevaporated antimony trisulphide films.Solid State Commun,1980,33(9):987~989
  • 8Grigas J,Meshkauskas J,Orliukas A.Dielectric properties of Sb2S3 at microwave-frequencies.Phys Stat Sol (a),1976,37(1):K39~K41
  • 9Ablowa M S,Andreev A A,Dedegkaev T T,et al.Switching effect in Sb2S3.Sov Phys Semicond,1976,10(6):629~631
  • 10Chockalingam M J,Rao K N,Rangarajan N,et al.Studies on sintered photoconductive layers of antimony trisulphide.J Phys D:Appl Phys,1970,3(11):1641~1644

同被引文献19

  • 1徐键,王公平,董建峰,沈祥.湿化学方法制备Sb2S3玻璃薄膜[J].武汉理工大学学报,2007,29(E01):281-283. 被引量:1
  • 2Yang Xinyu, Xiang Weidong, Zhang Xiyan, et al. Biomolecule-assisted synthesis of ribbon-like Sb2S3 nanos- tructure [J]. Advanced Materials Research, 2010, 101(97): 2 144-2 147.
  • 3Zheng Xiuwen, Xie Yi, Zhu Liying, et al. Growth of SbEE3 (E=S, Se) polygonal tubular crystals via a novel solvent-re- lief-self-seeding process[J]. Inorganic Chemistry, 2002, 41 (3): 455-461.
  • 4Yu S H, Shu L, Wu Y S, et al. Benzene-thermal synthesis and characterization of ultrafine powders of antimony sulfide [J]. Materials Research Bulletin, 1998, 33(8): 1207-1211.
  • 5Deng Zhengtao, Mansuripur Masud, Muscat Anthony J. Simple colloidal synthesis of single-crystal Sb-Se-S nan- otubes with composition dependent band-gap energy in the near-infrared[J]. Nano Letters, 2009, 9(5): 2 015-2 020.
  • 6Yang Jian, Zeng Jinghui, Yu Shuhong, et al. Pressure-con- trolled fabrication of stibnite nanorods by the solvothermal decomposition of a simple single-source precursor [J]. Chemistry of Materials, 2000, 12(10): 2 924-2 929.
  • 7Sheikhiabadi P G, Salavati-Niasari M, Davar F. Hydrother- mal synthesis and optical properties of antimony sulfide mi- cro and nano-size with different morphologies [J]. Materials Letters, 2012, 71(15): 168-171.
  • 8Han Qiaofeng, Lu Juan, Yang Xujie, et al. A Template-free route to Sb2S3 crystals with hollow olivary architectures [J]. Crystal Growth & Design, 2008, 8(2): 395-398.
  • 9Xu Yongbin, Ren Zhongming, Cao Guanghui, et al. A tem- plate-free route for controlled synthesis of dumbbell-like Sb2S3 microcrystals [J]. Crystal Research and Technology, 2009, 44(8): 851-856.
  • 10Zhang Ling, Chen Lei, Wan Hongqi, et al. Preparation of shuttle-like SbzS3 nanorod-bundles via a solvothermal ap- proach under alkaline condition [J]. Crystal Research and Technology, 2010, 45(2): 178-182.

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