摘要
Two different PAN precursors with various comonomers were wet-spun. The properties and structurul changes of PAN precursors and their evolution during preoxidation and carbonization process were characterized by the use of DSC , FTIR and traditional parameters, e g, tensile strength. It is demonstrated that acrylamide( AAM ) is very effective to make the DSC peak be separated compared to methyl acrylate ( MA ). As a result, carbon fibers developed from AAM-contained precursors have a better tenacity compared to those developed from MAcontained ones.
Two different PAN precursors with various comonomers were wet-spun. The properties and structurul changes of PAN precursors and their evolution during preoxidation and carbonization process were characterized by the use of DSC , FTIR and traditional parameters, e g, tensile strength. It is demonstrated that acrylamide( AAM ) is very effective to make the DSC peak be separated compared to methyl acrylate ( MA ). As a result, carbon fibers developed from AAM-contained precursors have a better tenacity compared to those developed from MAcontained ones.
基金
Funded bythe National Natural Science Foundation of China(No.50333070 and 50273002)