摘要
Using the laser granularity survey technology , logy, X-ray powder diffraction, scanning electron microscopy (SEM) and infrared spectrum anal)sis methods, we studied the microscopic structure and chemical bonds changes of β-C2 S monomineral under the high energy ball grinding function. The result indicates that, continuously under the mechanical power, β-C2 S crystal size would decrease, the micro strain and the effective Beff parameter would increase, and the amorphous phases would be presented. Furthermore, the mechanical power would cause Si-O bond broken and reorganized, the specific surface area would increase, the energy of micro-powder agglomeration vibration would be enhanced and the crystal would be disordered. Finally, β- C2 S was caused to have the mechanochemical change and the activity enhancement.
Using the laser granularity survey technology , logy, X-ray powder diffraction, scanning electron microscopy (SEM) and infrared spectrum anal)sis methods, we studied the microscopic structure and chemical bonds changes of β-C2 S monomineral under the high energy ball grinding function. The result indicates that, continuously under the mechanical power, β-C2 S crystal size would decrease, the micro strain and the effective Beff parameter would increase, and the amorphous phases would be presented. Furthermore, the mechanical power would cause Si-O bond broken and reorganized, the specific surface area would increase, the energy of micro-powder agglomeration vibration would be enhanced and the crystal would be disordered. Finally, β- C2 S was caused to have the mechanochemical change and the activity enhancement.
基金
Funded bythe State"973"High-Tech Item(No.2001CB610704-2)