期刊文献+

成核剂对PBS结晶性能及力学性能的影响 被引量:7

EFFECTS OF NUCLEATING AGENT ON CRYSTALLIZING PROPERTIES AND MECHANICAL PROPERTIES OF PBS
下载PDF
导出
摘要 运用差示扫描量热法、偏光显微镜和力学性能测试等分析手段,从晶形结构和宏观性能角度研究了4种成核剂对聚丁二酸丁二醇酯(PBS)结晶行为及力学性能的影响.结果表明,成核剂的加入细化了PBS球晶尺寸,球晶规整均匀,且结晶温度向高温方向移动,其中BenLa使PBS结晶温度移动了9.16℃,而成核改性PBS的力学性能较纯PBS也有所改善. The nucleating effects of 4 nucleating agents on the crystallization behavior and mechanical properties of PBS were studied microscopically and macroscopically by means of polarized optical microscopy, differential scanning calorimetry and mechanical properties. Comparing with pure PBS, nucleated PBS showed a higher crystallization temperature. The results indicate that nucleating agent BenLa increases melt-crystalline temperature of PBS by 9. 16 ℃. And polarized optical microscopy observations revealed that the spherulites became so small and even that the mechanical properties of PBS were improved.
出处 《北京工商大学学报(自然科学版)》 CAS 2006年第2期5-8,共4页 Journal of Beijing Technology and Business University:Natural Science Edition
基金 北京市委组织部"优秀人才专项资金"资助项目(20041D0500311)
关键词 PBS 成核剂 结晶性能 力学性能 PBS nucleating agent crystallizing property mechanical property
  • 相关文献

参考文献10

  • 1GB/T1040-92.塑料拉伸性能试验方法[S].[S].,..
  • 2GB/T1043-93,硬质塑料简支梁冲击试验方法[S].
  • 3GB/T3682-2000,热塑性塑料熔体质量流动速率和熔体体积流动速率的测定[S].
  • 4吴彤,郑晓秧,李燕立.PET工程塑料结晶性能的改善[J].北京服装学院学报(自然科学版),1999,19(2):10-15. 被引量:7
  • 5Romankiewicz A,Sterzynski T.Structural characterization of α and β nucleated isotactic polypropylene[J].Polymer International,2004,53(12):2086-2091.
  • 6Gao Xia,Liu Rui-gang.Influence of additives on the crystal structure and melting behavior of poly (ethylene-2,6-naphthalene dicarboxylate)[J].Journal of Polymer Science Part B:Polymer Physics,2004,42(2):296-301.
  • 7陈彦,徐懋,李育英,何嘉松.成核剂和促进剂对聚对苯二甲酸乙二酯结晶的影响[J].高分子学报,1999,9(1):7-14. 被引量:37
  • 8Feng Y,Jin X.Effect of nucleating agent addition on crystallization of isotactic polypropylene[J].Journal of Applied Polymer Science,1998,69 (10):2089-2095.
  • 9钱欣,程蓉,周珏,范文春.α和β成核剂对聚丙烯结晶行为的影响[J].塑料工业,2003,31(1):24-26. 被引量:38
  • 10Jang Gu-su,Cho Won-Jei.Crystallization behavior of polypropylene with or without sodium benzoate as a nucleating agent[J].Journal of Polymer Science Part B:Polymer Physics,2001,39(10):1001-1016.

二级参考文献10

  • 1关家玉 孙春荣 等.-[J].高分子通讯,1981,(6):451-451.
  • 2盖希特 R 陈振兴等(译).塑料添加剂手册[M].北京:中国石化出版社,1992.610-611.
  • 3李宗军.PET/TPEE共混体系的结晶及力学行为研究:硕士学位论文[M].北京:北京服装学院,1997..
  • 4Wang Xiaohui,高分子学报,1995年,46卷,163页
  • 5Tian D,Chin Chem Lett,1991年,2卷,905页
  • 6Liu Xiaoping,Polym,1989年,30卷,273页
  • 7关家玉,高分子通讯,1981年,6卷,449页
  • 8Beck H N,J Appl Polym Sci,1967年,11卷,673页
  • 9陈彦,徐懋.聚合物结晶成核剂作用的表征方法的比较和研究[J].高分子学报,1998,8(6):671-678. 被引量:40
  • 10窦强,王斌.β晶型聚丙烯的力学性能与结晶行为研究[J].功能高分子学报,2001,14(3):338-340. 被引量:55

共引文献95

同被引文献118

引证文献7

二级引证文献60

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部