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Bi过量和Mn掺杂的钛酸铋钠基无铅压电陶瓷 被引量:9

Mn-doped Lead-free Piezoelectric(Na,Bi)TiO_3 Based Ceramics Compensated with Extra Bi
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摘要 采用传统电子陶瓷制备工艺制备(1–y)(Na0.5Bi0.5)TiO3-yBa(ZrxTi1–x)O3无铅压电陶瓷,获得了d33高达185pC/N的0.94(Na0.5Bi0.5)TiO3-0.06Ba(Zr0.055Ti0.945)O3压电陶瓷。对Bi的挥发进行了补偿,添加过量Bi2O3(摩尔分数z=0.08)的钛酸铋钠基压电陶瓷,d33高达218pC/N。研究了Mn掺杂对钛酸铋钠基陶瓷压电、介电性能和损耗的影响,获得了高性能的无铅压电陶瓷,其中d33为214pC/N,kt为0.44,k33为0.52。 Lead-free piezoelectric ceramics (1-y)(Na0.5Bi0.5)TiO3-yBa(ZrxTi1-x)O3 were fabricated using the conventional ceramics technique. The composition 0.94(Na0.5Bi0.5)TiO3-0.06Ba(Zr0.055Ti0.945)O3 is obtained with d33 as high as 185 pC/N. By means of compensating the volatilization of Bi2O3, (Na, Bi)TiO3 based ceramics doped with extra 0.08%(mole fraction) Bi2O3 can be obtained with d33 as high as 195 pC/N. The effects of doping Mn on the piezoelectric, dielectric constant and dielectric loss are investigated, and the acquired (Na, Bi)TiO3 based lead-free piezoelectric ceramics have optimal properties: d33=214 pC/N, kt = 0.44, k33 = 0.52.
出处 《电子元件与材料》 CAS CSCD 北大核心 2006年第4期1-3,共3页 Electronic Components And Materials
基金 国家自然科学基金资助项目(50572056) 山东省重点自然科学基金资助项目(Z2003F04)
关键词 无机非金属材料 无铅压电陶瓷 掺杂 压电常数 机电耦合系数 inorganic non-metallic materials lead-free piezoelectric ceramics doping piezoelectric constant electromeehanieal coupling factors
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参考文献16

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