摘要
The compound [｛Pt4(en)4(NHCOtBu)4｝｛Tl(18-crown-6)｝2](PF6)6 has been synthesized by a simple one-potmulticomponent reaction. Its structure was determined by X-ray single crystal diffraction analysis. The cation ofthe compound consists of one linearly arranged [Pt4(en)4(NHCOtBu)4]4+ chain and two [Tl(18-crown-6)]+ ions located atthe two ends of the platinum chain. The complex crystallizes in a triclinic P1 with a=1.060 5(1), b=1.252 3(1), c=2.015(2) nm, α=107.430(2)°, β=91.032(2)°, γ=101.910(2)°, V=2.489 6(4) nm3, Z=2, R1=0.074 4, wR2(I>2σ(I))=0.2225, S=1.062. CCDC: 294083.
The compound [{Pt4（en）4（NHCO^tBu）4}{TI（18-crown-6）}2]（PF6）6 has been synthesized by a simple one-pot muhicomponent reaction. Its structure was determined by X-ray single crystal diffraction analysis. The cation of the compound consists of one linearly arranged [Pt4（en）4（NHCO^6Bu）4]^4＋ chain and two [Tl（18-crown-6）]^＋ ions located at the two ends of the platinum chain. The complex crystallizes in a triclinic P1 with a=1.060 5（1）, b=1.252 3（1）, c= 2.015（2） nm, α=107.430（2）°, β=91.032（2）°, γ=101.910（2）°, V=2.489 6（4） nm^3, Z=2, R1=0.074 4, wR2（I〉2σ（I））= 0.2225, S=1.062. CCDC： 294083.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2006年第4期761-764,共4页
Chinese Journal of Inorganic Chemistry
基金
浙江省自然科学基金(No.Y405435)资助课题。
关键词
晶体结构
铂
铊
18-冠-6
crystal structure
platinum
thallium
18-crown-6
