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Nitration of Wood Cellulose in HNO_3/Organic Solvent Medium 被引量:1

Nitration of Wood Cellulose in HNO_3/Organic Solvent Medium
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摘要 A steam explosion pretreatment at various severities was applied to pure wood cellulose; the influences of steam pretreatment on the morphological structure, the hydrophilic property and viscosity-average molecular weight of cellulose were evaluated. The nitration of steam-exploded cellulose was carried out in the nitrating agent medium (HNOa/organic solvent). The performance indexes of nitrocellulose, prepared from original and steam exploded samples, were determined by using the polarized optical microscope. The results show that after pretreatment the reactivity of the three hydroxyl groups in anhydroglucose unit of cellulose is improved, and the nitrogen content and the uniformity of NC from steam exploded cellulose observably increas. A steam explosion pretreatment at various severities was applied to pure wood cellulose; the influences of steam pretreatment on the morphological structure, the hydrophilic property and viscosity-average molecular weight of cellulose were evaluated. The nitration of steam-exploded cellulose was carried out in the nitrating agent medium (HNOa/organic solvent). The performance indexes of nitrocellulose, prepared from original and steam exploded samples, were determined by using the polarized optical microscope. The results show that after pretreatment the reactivity of the three hydroxyl groups in anhydroglucose unit of cellulose is improved, and the nitrogen content and the uniformity of NC from steam exploded cellulose observably increas.
出处 《Journal of Beijing Institute of Technology》 EI CAS 2006年第1期111-114,共4页 北京理工大学学报(英文版)
基金 theMinisterialLevelAdvancedResearchFoundation(40406030202)
关键词 NITROCELLULOSE wood cellulose nitrogen content UNIFORMITY nitrocellulose wood cellulose nitrogen content uniformity
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  • 1Yamane C,Mori M,Saito M,et al.Polymer J.,1970,14: 365-369.
  • 2Gusakov A V,Sinitsyn A P,Markov A V,et al.Journal of Biotechnology,2001,87(1): 83~90.
  • 3Yamashiki T,Matsui T,Saitoh M,et al.BrithishPolym.J.,1990,22(1): 73-83,121-128,201-212.
  • 4Yamashiki T,Matsui T,Saitoh M,et al.J.Appl.Polymer Sci.,1992,44: 691-698.
  • 5Kamide K,Okajima K,Matsui T,et al.Polymer J,1984,16(12): 857-866.

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  • 1Klemm D, Heublein B, Fink H, et al. Cellulose: fascinating biopolymer and sustainable raw material[J] Angew Chem Int Ed, 2005,44 : 3358-3393.
  • 2James I,Chang C H,Chen G,et al. The experience of waste minimization at a nitrocellulose manufacturing plant[J]. Resources, Conservation and Recycling, 2000(30):333-351.
  • 3Schur M O,Hoos B G. Nitration of purified wood fiber [J ]. Industrial and Engineering Chemistry, 1937,29(1) :26-44.
  • 4杨萌.木、棉纤维素硝化技术与产物性能分析[D].北京:北京理工大学,2008.

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