新型卟啉衍生物的合成与表征(英文)

Synthesis and Characterization of New Derivatives of Porphyrin

以1-溴-2,3,4,6-O-乙酰-D-葡萄糖(1)或氯乙醇分别与5-(对-氨基苯基)-10,15,20-三苯基卟啉(2)反应,制备5-(对-(-D- 葡萄糖氨基苯基)-10,15,20-三苯基卟啉(3)或5-(对-羟乙基氨基苯基)-10,15,20-三苯基卟啉(4)．该方法的反应条件温和,合成路线短,纯化方法简单．

Abstract ： 5-（p-β-D-glucoseaminophenyl ）-10, 15, 20-triphenyl porphyrin （ 3 ） and 5-（p-hydroxyethy laminophenyl）-10, 15,20-triphenyl porphyrin （4） were synthetized by reactions of 1-bromo-2,3, 4,6-O-aceto-β-D- glucose （1） or 2-chloroethanol with 5-（p-amino phenyl）-10,15,20-triphenyl porphyrin（2）, respectively. This process has the advantages of convenient manipulation, mild reaction conditions, and simple purifying method.