电解产生超氧同时制取酚类和环氧化物

Phenols and Epoxidex Prepared by Electrogenerated Superoxide Simultaneously

在利用氧电解还原产生的超氧离子Ｏ－２进行硝基卤苯的羟基取代生成酚类化合物过程中，产生的活性中间体能够完成烯烃的环氧化反应，同时得到硝基酚和环氧化物，对硝基苯酚与环氧化物（均苯环氧乙烷）的产率分别为４０％和７％。

Under the process of hydroxyl group nucleophilic substitution of nitrobrombenzene by electrogenerated superoxide ion O - 2 in aprotic solvent NO 2C 6H 4OO -, the active intermediate of the reaction used to epoxide olefin, with nitrophenol and epoxide being obtained simultaneously. The yeild of nitrophenol was 40 % and epoxied was 7 %.