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Study on the reactions of azo compounds with acyl halides mediated by Sm/TiCl_4

Study on the reactions of azo compounds with acyl halides mediated by Sm/TiCl_4
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摘要 Amides can be obtained in good to excellent yield by Sm/TiCl4 mediated reductive cleavage of N=N bond in azo compounds and successive acylation in one pot. It offers an alternative method for the synthesis of amides from very simple starting materials directly. Amides can be obtained in good to excellent yield by Sm/TiCl4 mediated reductive cleavage of N=N bond in azo compounds and successive acylation in one pot. It offers an alternative method for the synthesis of amides from very simple starting materials directly.
出处 《Journal of Zhejiang University-Science B(Biomedicine & Biotechnology)》 SCIE CAS CSCD 2006年第3期198-201,共4页 浙江大学学报(英文版)B辑(生物医学与生物技术)
基金 Project (No. 20072033) supported by the National Natural ScienceFoundation of China and Specialized Research Fund for the DoctoralProgram of Higher Education of China
关键词 Sm/TiCl4 酰胺 偶氮化合物 有机化学 Azo compounds Reduction Amides Sm/TiCl4
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