液相反应速度常数扩散极限值的计算和用途

Calculation and Application of Diffusion-Limited Rate Constants in Solutions

系统地介绍了稀溶液中反应速度常数扩散极限值的推导和计算法,并用实例说明了它在判断实验数据和机理假设的合理性以及在实验设计方面的应用。

The deduction process of the diffusion-limited kinetics was systematically and concisedy illustrated both for steady and non-steady states. Though the assumptions used for evaluating the diffusion-limted rate constants were plausible, their estimated values could still find some applications in the aspects of testing experimental da ta, judging the reaction mechanismas well as designing experiments.