摘要
用统计力学方法对无机叠氮化物慢速热分解中的两步重要反应进行了研究,求得了反应平衡转化率α随温度T和压力P变化的表达式,并对反应机理作了分析和探讨。还首次得到了叠氮基团的熵值。
Two important steps of slow thermal decomposition of azides have been studied using the method of statistical mechanics . Relations of the transform - ratio (α) of reactional equilibrium to temperature and pressure are formalized and the reaction mechanism is briefly discussed .Entropy of the azide -group is also abtained in this paper .
出处
《北京理工大学学报》
EI
CAS
CSCD
1990年第3期1-7,共7页
Transactions of Beijing Institute of Technology
关键词
无机叠氮化物
热分解
起爆机理
statistical physics , entropy , chemical equilibrium constant / thermal decomposition of azides , transform - ratio of reactional equilibrium .
