摘要
探讨安替吡啉偶氮Ⅲ与铈组稀土离子的显色反应,得出在pH=2的HCl介质中,试剂与铈组稀土元素形成4:1的蓝色络合物,λmax=720nm,ε=8.015×10^4L·mol^-1·cm^-1,稀土含量在0~1.2mg/L,符合比尔定律,选择性较好.在对人工合成样中的铈组稀土含量进行测定时,获得满意的结果。
Chromogenic reaction of cerium subgroup rare earths with antipyrylazo Ⅲ was studied. The results show that in hydrochloric acid media of pH = 2, antipyrylazo Ⅲ reacted with cerium subgroup rare earths to form a 4 : 1 blue complex, λmax = 720 nm, ε = 8. 015× 10^4 L · mol^- 1· cm^- 1, Beer' s law was obeyed in the concentration range of 0 -- 1.2 mg/L for rare earths elements. Antipyrylazo Ⅲ showed good selectivity. The method has been used for the spetrophotometric determination of cerium subgroup rare earths in synthesised sample with satisfactory results.
出处
《沈阳化工学院学报》
2006年第1期73-76,共4页
Journal of Shenyang Institute of Chemical Technolgy
关键词
安替吡啉偶氮Ⅲ
光度分析
铈组稀土
antipyrylazo Ⅲ
spetrophotometric analysis
cerium subgroup rare earths