摘要
A novel 5-aminoisophthalate compound, [Mn（C8H5NO4）·H2O]n·2nH2O 1, has been synthesized by the hydrothermal assembly of 5-aminoisophthalic acid with manganese acetate. Elemental analysis, X-ray crystal structure analyses, IR spectra, Fr-Raman and ESR were carried out for the structural determination and characterization of the title compound. Compound 1 crystallizes in triclinic, space group P1^- with a = 7.7562（2）, b = 8.6121（3）, c = 8.7107（2）A^°, α = 85.411（2）, β = 76.030（2）, γ = 66.510（2）°, V = 517.76（3）A^°3, MnC8H11NO7, Mr = 288.12, Z = 2, Dc = 1. 848 g/cm^3, μ= 1.300 mm^-1, F（000） = 294, R = 0.0381 and wR = 0.1043 for 1652 observed reflections （1 〉 20（/））.
A novel 5-aminoisophthalate compound, [Mn（C8H5NO4）·H2O]n·2nH2O 1, has been synthesized by the hydrothermal assembly of 5-aminoisophthalic acid with manganese acetate. Elemental analysis, X-ray crystal structure analyses, IR spectra, Fr-Raman and ESR were carried out for the structural determination and characterization of the title compound. Compound 1 crystallizes in triclinic, space group P1^- with a = 7.7562（2）, b = 8.6121（3）, c = 8.7107（2）A^°, α = 85.411（2）, β = 76.030（2）, γ = 66.510（2）°, V = 517.76（3）A^°3, MnC8H11NO7, Mr = 288.12, Z = 2, Dc = 1. 848 g/cm^3, μ= 1.300 mm^-1, F（000） = 294, R = 0.0381 and wR = 0.1043 for 1652 observed reflections （1 〉 20（/））.
基金
This work was supported by the National Natural Science Foundation of China (No. 20173063), the State Key Basic Research and Development Plan of China (001CB108906) and the NSF of Fujian Province (E0020001)
